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File:Oxidation of thiophene with trifluoroperacetic acid.png

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w:Thiophene is oxidised by w:trifluoroperacetic acid by two pathways. The major reaction involves the formation of thiophene-S-oxide which undergoes subsequent w:Diels-Alder-style dimerisation and further oxidation. The minor pathway involves the formation of thiophene-2,3-epoxide and subsequent rearrangement to thiophene-2-one. The reaction is discussed in the paper doi: doi:10.1021/jo0202177 and in the w:Encyclopedia of Reagents for Organic Synthesis article at doi: doi:10.1002/047084289X.rt254.pub2 .

The image was extracted and modified from this PDF of the EROS manuscript by w:user:EdChem and uploaded to Wikipedia on the same day. Whilst the EROS content is copyright protected, individual chemical structures and equations are ineligible for such protection.
来源 Transferred from en.wikipedia to Commons by FastilyClone using MTC!.
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Public domain 本图片是一个简单的结构式,因为其完全由公共财产信息组成,并不包含原始作者,不受著作权保护,所以属于公有领域

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The original description page was here. All following user names refer to en.wikipedia.
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2017-01-22 00:11:43 833× 450× EdChem [[Thiophene]] is oxidised by [[trifluoroperacetic acid]] by two pathways. The major reaction involves the formation of thiophene-''S''-oxide which undergoes subsequent [[Diels-Alder]]-style dimerisation and further oxidation. The minor pathway involv...

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当前2017年2月2日 (四) 00:582017年2月2日 (四) 00:58版本的缩略图833 × 450(37 KB)FastilyCloneTransferred from en.wikipedia (MTC!)

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