File:Oxidation of thiophene with trifluoroperacetic acid.png

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摘要

描述	w:Thiophene is oxidised by w:trifluoroperacetic acid by two pathways. The major reaction involves the formation of thiophene-S-oxide which undergoes subsequent w:Diels-Alder-style dimerisation and further oxidation. The minor pathway involves the formation of thiophene-2,3-epoxide and subsequent rearrangement to thiophene-2-one. The reaction is discussed in the paper doi: doi:10.1021/jo0202177 and in the w:Encyclopedia of Reagents for Organic Synthesis article at doi: doi:10.1002/047084289X.rt254.pub2 . The image was extracted and modified from this PDF of the EROS manuscript by w:user:EdChem and uploaded to Wikipedia on the same day. Whilst the EROS content is copyright protected, individual chemical structures and equations are ineligible for such protection.
来源	Transferred from en.wikipedia to Commons by FastilyClone using MTC!.
作者	本文件缺少作者信息。

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日期/时间	大小	用户	备注
2017-01-22 00:11:43	833× 450×	EdChem	[[Thiophene]] is oxidised by [[trifluoroperacetic acid]] by two pathways. The major reaction involves the formation of thiophene-''S''-oxide which undergoes subsequent [[Diels-Alder]]-style dimerisation and further oxidation. The minor pathway involv...