二甲基硫代甲酰胺

二甲基硫代甲酰胺
识别
CAS号	758-16-7
性质
化学式	C3H7NS
摩尔质量	89.16 g·mol−1
外观	淡黄色油状液体
密度	1.047 g·cm−3（0 °C）
沸点	96.5—97 °C（369.6—370.1 K）（12 mmHg）; 227—228 °C（500—501 K）
溶解性（水）	可溶于冷水，和热水混溶；; 可溶于苯、氯仿；; 难溶于石油醚
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

二甲基硫代甲酰胺是一种硫代酰胺，化学式为C₃H₇NS，它是味苦且有强烈气味的淡黄色油状液体。^[1]它可由二甲基甲酰胺和五硫化二磷^[2]或劳森试剂^[3]反应得到。它和三乙基硅基(羰基)(η⁵-环戊二烯基)(吡啶)合铁在苯中于室温反应，可以得到三乙基硅硫基(羰基)(二甲氨基亚甲基)(η⁵-环戊二烯基)合铁。^[4]它和甲基苯基亚砜在酸存在下反应，可以得到苯甲硫醚。^[5]

参考文献

^ ^1.0 ^1.1 ^1.2 ^1.3 Richard Willstätter, Theodor Wirth. Über Thioformamid. Berichte der deutschen chemischen Gesellschaft. 1909-04, 42 (2): 1908–1922 [2022-06-18]. ISSN 0365-9496. doi:10.1002/cber.19090420267 （英语）.
^ Thomas J. Curphey. Thionation with the Reagent Combination of Phosphorus Pentasulfide and Hexamethyldisiloxane. The Journal of Organic Chemistry. 2002-09-01, 67 (18): 6461–6473 [2022-06-18]. ISSN 0022-3263. doi:10.1021/jo0256742. （原始内容存档于2022-06-21）（英语）. （页面存档备份，存于互联网档案馆）
^ Rajender S. Varma, Dalip Kumar. Microwave-Accelerated Solvent-Free Synthesis of Thioketones, Thiolactones, Thioamides, Thionoesters, and Thioflavonoids. Organic Letters. 1999-09-01, 1 (5): 697–700 [2022-06-18]. ISSN 1523-7060. doi:10.1021/ol990629a. （原始内容存档于2019-07-19）（英语）. （页面存档备份，存于互联网档案馆）
^ Kozo Fukumoto, Akane Sakai, Tsukuru Oya, Hiroshi Nakazawa. Desulfurization of N,N-dimethylthioformamide by hydrosilane with the help of an iron complex. Isolation and characterization of an iron–carbene complex as an intermediate of CS double bond cleavage. Chemical Communications. 2012, 48 (32): 3809 [2022-06-18]. ISSN 1359-7345. doi:10.1039/c2cc17163e （英语）.
^ Haruo Kamijo, Toshio Takido, Toshikatsu Nakazawa, Kunio Itabashi, Manabu Seno. A NOVEL METHOD OF SULFIDE SYNTHESIS FROM SULFOXIDES WITH N,N -DIMETHYLTHIOFORMAMIDE. Phosphorus, Sulfur, and Silicon and the Related Elements. 1993-02, 82 (1-4): 207–210 [2022-06-18]. ISSN 1042-6507. doi:10.1080/10426509308047423 （英语）.

[Richard-1] 1.0 ^1.1 ^1.2 ^1.3 Richard Willstätter, Theodor Wirth. Über Thioformamid. Berichte der deutschen chemischen Gesellschaft. 1909-04, 42 (2): 1908–1922 [2022-06-18]. ISSN 0365-9496. doi:10.1002/cber.19090420267 （英语）.

[2] Thomas J. Curphey. Thionation with the Reagent Combination of Phosphorus Pentasulfide and Hexamethyldisiloxane. The Journal of Organic Chemistry. 2002-09-01, 67 (18): 6461–6473 [2022-06-18]. ISSN 0022-3263. doi:10.1021/jo0256742. （原始内容存档于2022-06-21）（英语）. （页面存档备份，存于互联网档案馆）

[3] Rajender S. Varma, Dalip Kumar. Microwave-Accelerated Solvent-Free Synthesis of Thioketones, Thiolactones, Thioamides, Thionoesters, and Thioflavonoids. Organic Letters. 1999-09-01, 1 (5): 697–700 [2022-06-18]. ISSN 1523-7060. doi:10.1021/ol990629a. （原始内容存档于2019-07-19）（英语）. （页面存档备份，存于互联网档案馆）

[4] Kozo Fukumoto, Akane Sakai, Tsukuru Oya, Hiroshi Nakazawa. Desulfurization of N,N-dimethylthioformamide by hydrosilane with the help of an iron complex. Isolation and characterization of an iron–carbene complex as an intermediate of CS double bond cleavage. Chemical Communications. 2012, 48 (32): 3809 [2022-06-18]. ISSN 1359-7345. doi:10.1039/c2cc17163e （英语）.

[5] Haruo Kamijo, Toshio Takido, Toshikatsu Nakazawa, Kunio Itabashi, Manabu Seno. A NOVEL METHOD OF SULFIDE SYNTHESIS FROM SULFOXIDES WITH N,N -DIMETHYLTHIOFORMAMIDE. Phosphorus, Sulfur, and Silicon and the Related Elements. 1993-02, 82 (1-4): 207–210 [2022-06-18]. ISSN 1042-6507. doi:10.1080/10426509308047423 （英语）.

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