1,3-苯并二氧戊环-5-硼酸

1,3-苯并二氧戊环-5-硼酸
	IUPAC名; 1,3-苯并二𫫇环戊熳-5-硼酸
别名	3,4-甲二氧基苯硼酸; 3,4-亚甲基二氧基苯硼酸; 苯并二𫫇茂-5-硼酸
识别
CAS号	94839-07-3
性质
化学式	C7H7BO4
摩尔质量	165.94 g·mol−1
外观	无色晶体
熔点	238-240 °C
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1,3-苯并二氧戊环-5-硼酸是一种有机化合物，化学式为C₇H₇BO₄。它可由5-溴-1,3-苯并二氧戊环为原料，和镁反应后再与硼酸三丁酯反应，水解后得到^[1]；或以1,3-苯并二氧戊环-5-胺为原料，重氮化后和二硼酸反应制得。^[2]它和氟化氢钾反应，可以得到1,3-苯并二氧戊环-5-基三氟硼酸钾。^[3]

参考文献

^ ^1.0 ^1.1 ^1.2 Mg Banwell, Cj Cowden. Convergent Routes to the [1,3]Dioxolo[4,5-j]phenanthridin-6(5H)-one and 2,3,4,4a-Tetrahydro[1,3]dioxolo[4,5-j]phenanthridin-6(5H)-one Nuclei. Application to Syntheses of the Amaryllidaceae Alkaloids Crinasiadine, N-Methylcrinasiadine and Trisphaeridine. Australian Journal of Chemistry. 1994, 47 (12): 2235 [2022-10-10]. ISSN 0004-9425. doi:10.1071/CH9942235 （英语）.
^ William Erb, Mathieu Albini, Jacques Rouden, Jérôme Blanchet. Sequential One-Pot Access to Molecular Diversity through Aniline Aqueous Borylation. The Journal of Organic Chemistry. 2014-11-07, 79 (21): 10568–10580 [2022-10-10]. ISSN 0022-3263. doi:10.1021/jo501665e. （原始内容存档于2022-10-16）（英语）.
^ Shigeki Matsunaga, Ayako Nakano, Yukino Okabe, Keitaro Matsuoka, Narumi Komami, Keito Watanabe, Masahiro Kojima, Tatsuhiko Yoshino. Generation of Monoaryl-λ3-iodanes from Arylboron Compounds through ipso-Substitution. HETEROCYCLES. 2021, 103 (2): 670 [2022-10-10]. ISSN 0385-5414. doi:10.3987/COM-20-S(K)45. （原始内容存档于2022-10-14）（英语）.

[banwell-1] 1.0 ^1.1 ^1.2 Mg Banwell, Cj Cowden. Convergent Routes to the [1,3]Dioxolo[4,5-j]phenanthridin-6(5H)-one and 2,3,4,4a-Tetrahydro[1,3]dioxolo[4,5-j]phenanthridin-6(5H)-one Nuclei. Application to Syntheses of the Amaryllidaceae Alkaloids Crinasiadine, N-Methylcrinasiadine and Trisphaeridine. Australian Journal of Chemistry. 1994, 47 (12): 2235 [2022-10-10]. ISSN 0004-9425. doi:10.1071/CH9942235 （英语）.

[2] William Erb, Mathieu Albini, Jacques Rouden, Jérôme Blanchet. Sequential One-Pot Access to Molecular Diversity through Aniline Aqueous Borylation. The Journal of Organic Chemistry. 2014-11-07, 79 (21): 10568–10580 [2022-10-10]. ISSN 0022-3263. doi:10.1021/jo501665e. （原始内容存档于2022-10-16）（英语）.

[3] Shigeki Matsunaga, Ayako Nakano, Yukino Okabe, Keitaro Matsuoka, Narumi Komami, Keito Watanabe, Masahiro Kojima, Tatsuhiko Yoshino. Generation of Monoaryl-λ3-iodanes from Arylboron Compounds through ipso-Substitution. HETEROCYCLES. 2021, 103 (2): 670 [2022-10-10]. ISSN 0385-5414. doi:10.3987/COM-20-S(K)45. （原始内容存档于2022-10-14）（英语）.

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