1-溴-3,5-二甲苯
外观
1-溴-3,5-二甲苯 | |
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识别 | |
CAS号 | 556-96-7 |
性质 | |
化学式 | C8H9Br |
摩尔质量 | 185.06 g·mol−1 |
沸点 | 204 °C[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
1-溴-3,5-二甲苯是一种有机化合物,化学式为C8H9Br。它可由3,5-二甲基苯胺经重氮化-溴化反应制得。[2]它和苯硼酸在乙酸钯催化下反应,得到3,5-二甲基联苯。[3]它和环己基胺在叔丁醇钠存在下反应,可以得到N-环己基-3,5-二甲基苯胺。[4]
参考文献
[编辑]- ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2022-3-6].
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- ^ Jairus L. Lamola, Paseka T. Moshapo, Cedric W. Holzapfel, Munaka Christopher Maumela. Evaluation of P-bridged biaryl phosphine ligands in palladium-catalysed Suzuki–Miyaura cross-coupling reactions. RSC Advances. 2021, 11 (43): 26883–26891 [2022-03-06]. ISSN 2046-2069. doi:10.1039/D1RA04947J (英语).
- ^ Kent O. Kirlikovali, Eunho Cho, Tyler J. Downard, Lilit Grigoryan, Zheng Han, Sooji Hong, Dahee Jung, Jason C. Quintana, Vanessa Reynoso, Sooihk Ro, Yi Shen, Kevin Swartz, Elizabeth Ter Sahakyan, Alex I. Wixtrom, Brandon Yoshida, Arnold L. Rheingold, Alexander M. Spokoyny. Buchwald–Hartwig amination using Pd( i ) dimer precatalysts supported by biaryl phosphine ligands. Dalton Transactions. 2018, 47 (11): 3684–3688 [2022-03-06]. ISSN 1477-9226. doi:10.1039/C8DT00119G (英语).