三甲酰胺
| 三甲酰胺 | |
|---|---|
| |
| 英文名 | Triformamide |
| 識別 | |
| CAS號 | 25891-31-0 
|
| SMILES |
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| 性質 | |
| 化學式 | C3H3NO3 |
| 摩爾質量 | 101.06 g·mol⁻¹ |
| 密度 | 1.307 ± 0.06 g·cm−3（20 °C）[1] |
| 沸點 | 198 ± 23 °C[1] |
| 溶解性（水） | 33 g[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
三甲酰胺是一種有機化合物，為新型的甲酰化試劑，化學式為C3H3NO3。[2]它可由二甲酰氨基鈉和鹵化試劑（如三氯化磷、氯化亞碸等）在乙腈中於低溫反應得到。[3][4]它可以和酚在二甲酰氨基鈉或三氟甲磺酸鐠的催化下反應，生成芳基甲酸酯。[5]
參考文獻
[編輯]- ^ 1.0 1.1 1.2 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-7-30]
- ^ Bagno, Alessandro; Kantlehner, Willi; Scherr, Oliver; Vetter, Jens; Ziegler, Georg. New Formylating Agents − Preparative Procedures and Mechanistic Investigations. European Journal of Organic Chemistry. 2001, 2001 (15): 2947. ISSN 1434-193X. doi:10.1002/1099-0690(200108)2001:15<2947::AID-EJOC2947>3.0.CO;2-R.
- ^ Kantlehner, Willi; Ziegler, Georg; Scherr, Oliver; Kreß, Ralf; Leonhardt, Sylvia. Orthoamide und Iminiumsalze, LXXXIII [1]. Die Synthese von starken Formylierungsmitteln im präparativen Großmaßstab: Triformamid (Triformylamin) / Orthoamides and Iminium Salts LXXXIII [1]. The Synthesis of Strong Formylating Reagents on Large Preparative Scale: Triformamide (Triformylamine). Zeitschrift für Naturforschung B. 2014, 69 (3): 332–350. ISSN 1865-7117. doi:10.5560/znb.2014-3269.
- ^ Schall, A.; Reiser, O. Arenecarbaldehydes: synthesis by formylation of arene-hydrogen bonds. Science of Synthesis, 2007. 25 [2006]. 605-653. CODEN: SSCYJ9
- ^ Ziegler, Georg; Kantlehner, Willi. Orthoamides, LVI [1]. A New Method of Wide Scope for the Preparation of Aryl Formates. Zeitschrift für Naturforschung B. 2001, 56 (11): 1172–1177. ISSN 1865-7117. doi:10.1515/znb-2001-1112.