4-(1-環戊烯基)嗎啉
外觀
4-(1-環戊烯基)嗎啉 | |
---|---|
識別 | |
CAS號 | 936-52-7 |
性質 | |
化學式 | C9H15NO |
摩爾質量 | 153.22 g·mol−1 |
熔點 | 122—127 °C(395—400 K)(分解)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
4-(1-環戊烯基)嗎啉或N-(1-環戊烯基)嗎啉是一種有機化合物,化學式為C9H15NO。它可以環戊酮和嗎啉為原料反應製得[2]。它和4,5-二氰基噠嗪反應,可以得到2,3-二氫-1H-茚-5,6-二腈[3]。它和異氰酸苯酯反應,得到N-苯基-2-(4-嗎啉基)環戊烯甲酰胺[4]。
參考文獻
[編輯]- ^ Huenig, Siegfried; Huebner, Klaus; Benzing, Erhard. Syntheses with enamines. VII. Addition of isocyanates and isothiocyanates to enamines. Chemische Berichte, 1962. 95: 926-936.
- ^ Ghalia Bouhalleb, Ahmed Meddeb, Noura Fakhar Bourguiba, Julien Legros, Giovanni Poli, Farhat Rezgui. First Zinc Bromide Promoted Annulative Domino Reactions between Enamines and Cyclic Morita–Baylis–Hillman Alcohols: Synthesis of N,O-Ketals. Synlett. 2020-08, 31 (13): 1282–1286 [2021-07-12]. ISSN 0936-5214. doi:10.1055/s-0040-1707467 (英語).
- ^ Stefania Turchi, Rodolfo Nesi, Donatella Giomi. Reactions of 4,5-dicyanopyridazine with alkynes and enamines: A new straightforward complementary route to 4-mono- and 4,5-disubstituted phthalonitriles. Tetrahedron. 1998-02, 54 (9): 1809–1816 [2021-07-12]. doi:10.1016/S0040-4020(97)10389-1. (原始內容存檔於2018-06-27) (英語).
- ^ Ried, Walter; Kaeppeler, Walter. Reactions with cyclic enamines. I. Reaction of cycloalkeneamines with phenyl isocyanate and phenylisothiocyanate. Justus Liebigs Annalen der Chemie, 1964. 673. 132-136. ISSN: 0075-4617.