硫代樟脑

硫代樟脑
识别
CAS号	7519-74-6
性质
化学式	C10H16S
摩尔质量	168.3 g·mol−1
熔点	119 °C（392 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

硫代樟脑是一种有机硫化合物，化学式为C₁₀H₁₆S。它可由樟脑和五硫化二磷^[2]^[3]、劳森试剂^[4]等硫化试剂反应得到。在甲基三氧化铼的催化下，它可以被过氧化氢氧化为S-氧化硫代樟脑；^[5]过氧化氢/氯化亚砜也可将其转化为樟脑。^[6]

参考文献

^ Schaumann, Ernst; Wriede, Ulrich; Ruehter, Gerd. New access to thiocarbonyl compounds. Angewandte Chemie, 1983. 95 (1): 52-53. ISSN 0044-8249.
^ Vivek Polshettiwar, Manisha Nivsarkar, Deepak Paradashani, M.P. Kaushik. Thionation of carbonyl compounds using phosphorus pentasulfide and hexamethyldisiloxane under microwave irradiations. Journal of Chemical Research. 2004-07, 2004 (7): 474–476 [2022-04-10]. ISSN 1747-5198. doi:10.3184/0308234042037149 （英语）.
^ Vivek Polshettiwar, M.P. Kaushik. A new, efficient and simple method for the thionation of ketones to thioketones using P4S10/Al2O3. Tetrahedron Letters. 2004-08, 45 (33): 6255–6257 [2022-04-10]. doi:10.1016/j.tetlet.2004.06.091. （原始内容存档于2018-06-25）（英语）.
^ David L. Gamble, William P. Hems, Brian Ridge. Studies on the preparation of camphorylidene derivatives of α-amino acids. Journal of the Chemical Society, Perkin Transactions 1. 2001, (3): 248–260 [2022-04-10]. doi:10.1039/b007659g.
^ Ruili Huang, James H. Espenson. A Convenient Preparation of Sulfines (R 2 CSO) from Thioketones. The Journal of Organic Chemistry. 1999-09-01, 64 (18): 6935–6936 [2022-04-10]. ISSN 0022-3263. doi:10.1021/jo990967p （英语）.
^ Kiumars Bahrami, Mohammad M. Khodaei, Azita Farrokhi. H2O2/SOCl2: a useful reagent system for the conversion of thiocarbonyls to carbonyl compounds. Tetrahedron. 2009-09, 65 (36): 7658–7661 [2022-04-10]. doi:10.1016/j.tet.2009.06.110. （原始内容存档于2018-06-29）（英语）.

[1] Schaumann, Ernst; Wriede, Ulrich; Ruehter, Gerd. New access to thiocarbonyl compounds. Angewandte Chemie, 1983. 95 (1): 52-53. ISSN 0044-8249.

[2] Vivek Polshettiwar, Manisha Nivsarkar, Deepak Paradashani, M.P. Kaushik. Thionation of carbonyl compounds using phosphorus pentasulfide and hexamethyldisiloxane under microwave irradiations. Journal of Chemical Research. 2004-07, 2004 (7): 474–476 [2022-04-10]. ISSN 1747-5198. doi:10.3184/0308234042037149 （英语）.

[3] Vivek Polshettiwar, M.P. Kaushik. A new, efficient and simple method for the thionation of ketones to thioketones using P4S10/Al2O3. Tetrahedron Letters. 2004-08, 45 (33): 6255–6257 [2022-04-10]. doi:10.1016/j.tetlet.2004.06.091. （原始内容存档于2018-06-25）（英语）.

[4] David L. Gamble, William P. Hems, Brian Ridge. Studies on the preparation of camphorylidene derivatives of α-amino acids. Journal of the Chemical Society, Perkin Transactions 1. 2001, (3): 248–260 [2022-04-10]. doi:10.1039/b007659g.

[5] Ruili Huang, James H. Espenson. A Convenient Preparation of Sulfines (R 2 CSO) from Thioketones. The Journal of Organic Chemistry. 1999-09-01, 64 (18): 6935–6936 [2022-04-10]. ISSN 0022-3263. doi:10.1021/jo990967p （英语）.

[6] Kiumars Bahrami, Mohammad M. Khodaei, Azita Farrokhi. H2O2/SOCl2: a useful reagent system for the conversion of thiocarbonyls to carbonyl compounds. Tetrahedron. 2009-09, 65 (36): 7658–7661 [2022-04-10]. doi:10.1016/j.tet.2009.06.110. （原始内容存档于2018-06-29）（英语）.

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