2,5-二甲基-1,4-二硫杂-2,5-环己二醇
| 2,5-二甲基-1,4-二硫杂-2,5-环己二醇 | |
|---|---|
| |
| 识别 | |
| CAS号 | 55704-78-4 
|
| 性质 | |
| 化学式 | C6H12O2S2 |
| 摩尔质量 | 180.29 g·mol−1 |
| 熔点 | 117-118 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
2,5-二甲基-1,4-二硫杂-2,5-环己二醇是一种有机化合物，化学式为C6H12O2S2。它可由氯丙酮和硫氢化钠为原料反应制得。[2]它在乙腈中和亚苄基丙二腈加热反应，可以得到二氢-4-羟基-4-甲基-2-苯基-3,3(2H)-噻吩二甲腈。[3]
参考文献
[编辑]- ^ Thiel, Max; Asinger, Friedrich. Concomitant action of elementary sulfur and gaseous ammonia on ketones. IV. Concomitant action of sulfur and ammonia on acetone. Justus Liebigs Annalen der Chemie, 1957. 610: 17-24. ISSN 0075-4617.
- ^ Brown, Michael D.; Gillon, David W.; Meakins, G. Denis; Whitham, Gordon H. A new general synthesis of 2-(N-mono- and N-disubstituted amino)thiazoles. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985. 8: 1623-1626. ISSN 0300-922X.
- ^ Itaru Suzuki, Yuki Sakamoto, Yuta Seo, Yoriko Ninomaru, Kodai Tokuda, Ikuya Shibata. Synthesis of 5-Membered Sulfur Heterocycles via Tin-Catalyzed Annulation of Mercapto Ketones with Activated Alkenes. The Journal of Organic Chemistry. 2020-02-21, 85 (4): 2759–2769 [2022-03-24]. ISSN 0022-3263. doi:10.1021/acs.joc.9b03055.