4-羧基苯硼酸

4-羧基苯硼酸
英文名	4-boronobenzoic acid
识别
CAS号	14047-29-1
性质
化学式	C7H7BO4
摩尔质量	165.94 g·mol−1
熔点	219—220 °C（492—493 K）
沸点	236—237 °C（509—510 K）（分解）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

4-羧基苯硼酸是一种有机硼酸，化学式为C₇H₇BO₄。

合成

4-溴苯硼酸和硼酸三异丙酯反应，先后用正丁基锂和盐酸处理，可以得到4-羧基苯硼酸。^[3]4-甲基苯硼酸^[4]或4-甲酰基苯硼酸^[5]的氧化反应也可用于制备4-羧基苯硼酸。

参考文献

^ H. R. Snyder, Albert J. Reedy, Wm. J. Lennarz. Synthesis of Aromatic Boronic Acids. Aldehydo Boronic Acids and a Boronic Acid Analog of Tyrosine 1. Journal of the American Chemical Society. 1958-2, 80 (4): 835–838 [2019-04-19]. ISSN 0002-7863. doi:10.1021/ja01537a021. （原始内容存档于2019-09-18）（英语）. 请检查|date=中的日期值 (帮助)
^ Paweł Kurach, Sergiusz Luliński, Janusz Serwatowski. One-Pot Generation of Lithium (Lithiophenyl)trialkoxyborates from Substituted Dihalobenzenes (Hal = Br, I) and Their Derivatization with Electrophiles. European Journal of Organic Chemistry. 2008-6, 2008 (18): 3171–3178 [2019-04-19]. doi:10.1002/ejoc.200800245 （英语）. 请检查|date=中的日期值 (帮助)
^ Wenjie Li, Dorian P. Nelson, Mark S. Jensen, R. Scott Hoerrner, Dongwei Cai, Robert D. Larsen, Paul J. Reider. An Improved Protocol for the Preparation of 3-Pyridyl- and Some Arylboronic Acids. The Journal of Organic Chemistry. 2002-7, 67 (15): 5394–5397 [2019-04-19]. ISSN 0022-3263. doi:10.1021/jo025792p. （原始内容存档于2019-09-18）（英语）. 请检查|date=中的日期值 (帮助)
^ Jan C. Namyslo, Dieter E. Kaufmann. Chemical improvement of surfaces. Part 1: Novel functional modification of wood with covalently bound organoboron compounds. Holzforschung. 2009-01-01, 63 (5) [2019-04-19]. ISSN 1437-434X. doi:10.1515/HF.2009.112. （原始内容存档于2018-06-07）.
^ Safacan Kolemen, Tugba Ozdemir, Dayoung Lee, Gyoung Mi Kim, Tugce Karatas, Juyoung Yoon, Engin U. Akkaya. Remote-Controlled Release of Singlet Oxygen by the Plasmonic Heating of Endoperoxide-Modified Gold Nanorods: Towards a Paradigm Change in Photodynamic Therapy. Angewandte Chemie International Edition. 2016-03-07, 55 (11): 3606–3610 [2019-04-19]. doi:10.1002/anie.201510064 （英语）.

[1] H. R. Snyder, Albert J. Reedy, Wm. J. Lennarz. Synthesis of Aromatic Boronic Acids. Aldehydo Boronic Acids and a Boronic Acid Analog of Tyrosine 1. Journal of the American Chemical Society. 1958-2, 80 (4): 835–838 [2019-04-19]. ISSN 0002-7863. doi:10.1021/ja01537a021. （原始内容存档于2019-09-18）（英语）. 请检查|date=中的日期值 (帮助)

[2] Paweł Kurach, Sergiusz Luliński, Janusz Serwatowski. One-Pot Generation of Lithium (Lithiophenyl)trialkoxyborates from Substituted Dihalobenzenes (Hal = Br, I) and Their Derivatization with Electrophiles. European Journal of Organic Chemistry. 2008-6, 2008 (18): 3171–3178 [2019-04-19]. doi:10.1002/ejoc.200800245 （英语）. 请检查|date=中的日期值 (帮助)

[3] Wenjie Li, Dorian P. Nelson, Mark S. Jensen, R. Scott Hoerrner, Dongwei Cai, Robert D. Larsen, Paul J. Reider. An Improved Protocol for the Preparation of 3-Pyridyl- and Some Arylboronic Acids. The Journal of Organic Chemistry. 2002-7, 67 (15): 5394–5397 [2019-04-19]. ISSN 0022-3263. doi:10.1021/jo025792p. （原始内容存档于2019-09-18）（英语）. 请检查|date=中的日期值 (帮助)

[4] Jan C. Namyslo, Dieter E. Kaufmann. Chemical improvement of surfaces. Part 1: Novel functional modification of wood with covalently bound organoboron compounds. Holzforschung. 2009-01-01, 63 (5) [2019-04-19]. ISSN 1437-434X. doi:10.1515/HF.2009.112. （原始内容存档于2018-06-07）.

[5] Safacan Kolemen, Tugba Ozdemir, Dayoung Lee, Gyoung Mi Kim, Tugce Karatas, Juyoung Yoon, Engin U. Akkaya. Remote-Controlled Release of Singlet Oxygen by the Plasmonic Heating of Endoperoxide-Modified Gold Nanorods: Towards a Paradigm Change in Photodynamic Therapy. Angewandte Chemie International Edition. 2016-03-07, 55 (11): 3606–3610 [2019-04-19]. doi:10.1002/anie.201510064 （英语）.

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