N-亚磺酰基苯胺
| N-亚磺酰基苯胺 | |
|---|---|
| |
| IUPAC名 (Phenylimino)-λ4-sulfanone[1] | |
| 别名 | N-thionylaniline, phenyliminooxosulfurane, N-sulfinylbenzenamine |
| 识别 | |
| CAS号 | 1122-83-4 
|
| PubChem | 70739 |
| ChemSpider | 63904 |
| SMILES |
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| 性质 | |
| 化学式 | C6H5NSO |
| 摩尔质量 | 139.18 g·mol⁻¹ |
| 外观 | yellowish oil |
| 密度 | 1.236 g/mL |
| 沸点 | 88–95 °C (17–20 mm.) |
| 危险性 | |
GHS危险性符号 
| |
| GHS提示词 | Danger |
| H-术语 | H315, H319, H334, H335 |
| P-术语 | P261, P264, P271, P280, P285, P302+352, P304+340, P304+341, P305+351+338, P312, P321, P332+313, P337+313, P342+311 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
N-亚磺酰基苯胺是有机硫化合物，化学式C6H5NSO，这亚磺酰胺是稻草色液体；亲双烯体；[2]在金属有机化合物中可作为配体。[3]
制备及结构
[编辑]- 3 PhNH2 + SOCl2 → PhNSO + 2 [PhNH3]Cl
单晶衍射表明结构和二氧化硫或二亚氨基硫有相似之处，碳－氮＝硫＝氧二面角为–1.60°。[5]
参考文献
[编辑]- ^ International Union of Pure and Applied Chemistry. Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. The Royal Society of Chemistry. 2014: 1032. ISBN 978-0-85404-182-4. doi:10.1039/9781849733069.
- ^ Kresze, G.; Wucherpfennig, W. New Methods of Preparative Organic Chemistry V: Organic Syntheses with Imides of Sulfur Dioxide. Angewandte Chemie International Edition in English. 1967, 6 (2): 149–167. PMID 4962859. doi:10.1002/anie.196701491.
- ^ Hill, A. F., "Organotransition metallic chemistry of sulfur dioxide analogs", Adv. Organomet. Chem. 1994, 36, 159-227
- ^ Rajagopalan, S.; Advani, B. G.; Talaty, C. N. Diphenylcarbodiimide. Organic Syntheses. 1969, 49: 70. doi:10.15227/orgsyn.049.0070..
- ^ Romano, R.M; Della Védova, C.O; Boese, R. A Solid State Study of the Configuration and Conformation of O=S=N–R (R=C6H5 and C6H3(CH3–CH2)2-2,6). Journal of Molecular Structure. 1999, 475 (1): 1–4. Bibcode:1999JMoSt.475....1R. doi:10.1016/S0022-2860(98)00439-6.