氟钛酸盐
外观
氟钛酸盐又称六氟合钛酸盐,通常指含有+4价钛的TiF62-盐类。
制备
[编辑]氟钛酸盐可由六氟合钛酸和金属或其碳酸盐、氢氧化物反应得到:[1]
- Fe + H2TiF6 → FeTiF6 + H2↑
钛(III)氟配合物
[编辑]+3价钛也能形成氟配合物,如TiF52-和TiF63-。[2]
参考文献
[编辑]- ^ TE Jenkins, J Lewis. A Raman investigation of some metal (II) hexafluorosilicate (IV) and hexafluorotitanate (IV) salts. Spectrochimica Acta Part A: Molecular Spectroscopy. 1981, 37(1):47-50. doi 10.1016/0584-8539(81)80132-8
- ^ L Herman, G Mitra. Ammonium zinc hexafluorotitanate(III) hexahydrate: NH4ZnTiF6·6H2O. Journal of Fluorine Chemistry, 1972, 1(4):498-499. doi 10.1016/S0022-1139(00)82971-1