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氯乙酸钾

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氯乙酸钾
识别
CAS号 7748-25-6  checkY
性质
化学式 C2H2ClKO2
摩尔质量 132.59 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

氯乙酸钾是一种氯乙酸盐,化学式为ClCH2COOK,它可以和氧化汞反应。[1]它的酸式盐KH(ClCH2COO)2是已知的。[2]

制备

[编辑]

氯乙酸钾可由氯乙酸乙烯酯苯酚钾在无水甲醇中反应得到。[3]它也可由氯乙酸氢氧化钾反应制得。[4]

参考文献

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  1. ^ Pr Wells, W Kitching. The Reaction of Aqueous Potassium Chloroacetate with Mercuric Oxide. Australian Journal of Chemistry. 1963, 16 (6): 1123 [2022-10-09]. ISSN 0004-9425. doi:10.1071/CH9631123 (英语). 
  2. ^ Pokorny, Josef. Ammonium and alkali metal haloacetates. III. Solubility determination and investigation of the ternary diagram alkali metal chloroacetate-chloroacetic acid-water at 20°(捷克文). Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, B: Anorganicka Chemie a Technologie, 1972. B14: 167-173. ISSN 0551-8393.
  3. ^ Martin Hauser. The Reaction of Vinyl Chloroacetate with Some Nucleophilic Reagents. The Journal of Organic Chemistry. 1962-01, 27 (1): 43–46 [2022-10-09]. ISSN 0022-3263. doi:10.1021/jo01048a010. (原始内容存档于2022-10-17) (英语). 
  4. ^ A.K. Mishra, N.K. Kaushik. Synthesis, characterization, cytotoxicity, antibacterial and antifungal evaluation of some new platinum (IV) and palladium (II) complexes of thiodiamines. European Journal of Medicinal Chemistry. 2007-10, 42 (10): 1239–1246 [2022-10-09]. doi:10.1016/j.ejmech.2007.03.017. (原始内容存档于2018-06-14) (英语).