苯乙炔亚铜

苯乙炔亚铜
识别
CAS号	13146-23-1
性质
化学式	C8H5Cu
摩尔质量	164.67 g·mol−1
外观	黄色固体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

苯乙炔亚铜是一种有机铜化合物，化学式为{C₈H₅Cu}_n。它可由苯乙炔和二氨合铜(I)盐反应制得。^[1]它可以和三乙基膦反应，得到(C₂H₅)₃PCuC≡CPh（Ph=C₆H₅）。^[2]它和一种膦配体L（L=Ph₂PCH₂(CH₂OCH₂)₂CH₂PPh₂）反应，可以得到亮黄色的Cu₄(C≡CPh)₄L₂。^[3]

参考文献

^ ^1.0 ^1.1 SUBSTITUTION OF ARYL HALIDES WITH COPPER(I) ACETYLIDES: 2-PHENYLFURO[3,2-b]PYRIDINE. Organic Syntheses (Organic Syntheses). 1972, 52: 128. ISSN 0078-6209. doi:10.15227/orgsyn.052.0128.
^ Blake, D.; Calvin, G.; Coates, G. E. Copper and silver ethynyl coördination complexes. Proceedings of the Chemical Society, London, 1959: 396-397. ISSN 0369-8718.
^ Chan, Wing-Han; Zhang, Zheng-Zhi; Mak, Thomas C.W; Che, Chi-Ming. A highly luminescent tetranuclear copper(I) cluster: structure and photophysical properties. Journal of Organometallic Chemistry (Elsevier BV). 1998, 556 (1-2): 169–172. ISSN 0022-328X. doi:10.1016/s0022-328x(97)00702-x.

[orgsyn-1] 1.0 ^1.1 SUBSTITUTION OF ARYL HALIDES WITH COPPER(I) ACETYLIDES: 2-PHENYLFURO[3,2-b]PYRIDINE. Organic Syntheses (Organic Syntheses). 1972, 52: 128. ISSN 0078-6209. doi:10.15227/orgsyn.052.0128.

[2] Blake, D.; Calvin, G.; Coates, G. E. Copper and silver ethynyl coördination complexes. Proceedings of the Chemical Society, London, 1959: 396-397. ISSN 0369-8718.

[3] Chan, Wing-Han; Zhang, Zheng-Zhi; Mak, Thomas C.W; Che, Chi-Ming. A highly luminescent tetranuclear copper(I) cluster: structure and photophysical properties. Journal of Organometallic Chemistry (Elsevier BV). 1998, 556 (1-2): 169–172. ISSN 0022-328X. doi:10.1016/s0022-328x(97)00702-x.

[1]

[2]

[3]