氟化磷酸鹽

氟化磷酸鹽^[1]是由氟離子（F−
）和磷酸根（PO3−
4）構成的混合陰離子化合物。自然界中常見的氟化磷酸鹽礦物有氟磷灰石（氟化三磷酸五鈣，Ca₅(PO₄)₃F）、氟磷鎂石（英語：Wagnerite）（(Mg,Fe)₂PO₄F）等。人工合成的M^IM^IIPO₄F（M^I=Na, Li；M^II=Fe, Mn, Co, Ni）可用於電化學的正極材料。^[2]

合成

氟化磷酸鹽可由磷酸二氫銨-氟化鈉和金屬鹽體系的固相法合成，或通過含磷酸-氟化鈉（氫氟酸^[3]）的水熱體系反應得到。^[4]反應中也會加入其它試劑，如硼酸作為礦化劑。^[5]

參考文獻

^ 中國化學會無機化學命名原則 1980. pp. 19. (III)混鹽和復鹽. 「……在名稱中將分子量較小者放在前面」
^ 鄭寅. 鈉離子電池正極材料氟化磷酸鹽的物理和電化學性質. 廈門大學. 2014.
^ Gwenaël Corbel, Georges Courbion, Françoise Le Berre, Marc Leblanc, Jean-Marc Le Meins, Vincent Maisonneuve, Nicolas Mercier. Synthesis from solutions and properties of various metal fluorides and fluoride salts. Journal of Fluorine Chemistry. 2001-02, 107 (2): 193–198 [2022-05-29]. doi:10.1016/S0022-1139(00)00358-4. （原始內容存檔於2019-11-01）（英語）.
^ Brian L. Ellis, W. R. Michael Makahnouk, W. N. Rowan-Weetaluktuk, D. H. Ryan, Linda F. Nazar. Crystal Structure and Electrochemical Properties of A 2 MPO 4 F Fluorophosphates (A = Na, Li; M = Fe, Mn, Co, Ni). Chemistry of Materials. 2010-02-09, 22 (3): 1059–1070 [2022-05-29]. ISSN 0897-4756. doi:10.1021/cm902023h. （原始內容存檔於2022-06-03）（英語）.
^ Feng Xu, Guang Peng, Chensheng Lin, Dan Zhao, Bingxuan Li, Ge Zhang, Shunda Yang, Ning Ye. Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence. Journal of Materials Chemistry C. 2020, 8 (14): 4965–4972 [2022-05-29]. ISSN 2050-7526. doi:10.1039/D0TC00281J （英語）.

[1] 中國化學會無機化學命名原則 1980. pp. 19. (III)混鹽和復鹽. 「……在名稱中將分子量較小者放在前面」

[2] 鄭寅. 鈉離子電池正極材料氟化磷酸鹽的物理和電化學性質. 廈門大學. 2014.

[3] Gwenaël Corbel, Georges Courbion, Françoise Le Berre, Marc Leblanc, Jean-Marc Le Meins, Vincent Maisonneuve, Nicolas Mercier. Synthesis from solutions and properties of various metal fluorides and fluoride salts. Journal of Fluorine Chemistry. 2001-02, 107 (2): 193–198 [2022-05-29]. doi:10.1016/S0022-1139(00)00358-4. （原始內容存檔於2019-11-01）（英語）.

[4] Brian L. Ellis, W. R. Michael Makahnouk, W. N. Rowan-Weetaluktuk, D. H. Ryan, Linda F. Nazar. Crystal Structure and Electrochemical Properties of A 2 MPO 4 F Fluorophosphates (A = Na, Li; M = Fe, Mn, Co, Ni). Chemistry of Materials. 2010-02-09, 22 (3): 1059–1070 [2022-05-29]. ISSN 0897-4756. doi:10.1021/cm902023h. （原始內容存檔於2022-06-03）（英語）.

[5] Feng Xu, Guang Peng, Chensheng Lin, Dan Zhao, Bingxuan Li, Ge Zhang, Shunda Yang, Ning Ye. Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence. Journal of Materials Chemistry C. 2020, 8 (14): 4965–4972 [2022-05-29]. ISSN 2050-7526. doi:10.1039/D0TC00281J （英語）.

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