苯并[a]咔唑
| 苯並[a]咔唑 | |
|---|---|
carbazole.svg)
| |
| 別名 | 11H-苯並[a]咔唑 |
| 識別 | |
| CAS號 | 239-01-0 
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| SMILES |
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| 性質 | |
| 化學式 | C16H11N |
| 摩爾質量 | 217.27 g·mol−1 |
| 外觀 | 白色固體[1] |
| 熔點 | 230-231 °C[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
苯並[a]咔唑是一種稠雜環有機物，化學式為C16H11N。有多種方法可以合成該化合物[2]，例如，它可由N-(2-溴苯基)-1-萘胺和叔丁醇鉀在液氨中光照反應製得；[3]2-(1-萘氨基)苯甲酸在乙酸鈀、鄰菲囉啉和碳酸銀催化下於1,4-二氧六環中脫羧關環，也能得到該化合物。[4]它和NBS反應，可以得到5-溴苯並[a]咔唑。[5]
參考文獻
[編輯]- ^ 1.0 1.1 Indium-Catalyzed Annulation of 2-Aryl- and 2-Heteroarylindoles with Propargyl Ethers: Concise Synthesis and Photophysical Properties of Diverse Aryl- and Heteroaryl-Annulated[a]carbazoles. J. Am. Chem. Soc. 2008. doi:10.1021/ja803954e
- ^ Wu, F., Huang, W., Yiliqi, Yang, J., & Gu, Y. (2018). Relay Catalysis of Bismuth Trichloride and Byproduct Hydrogen Bromide Enables the Synthesis of Carbazole and Benzo[α]carbazoles from Indoles and α-Bromoacetaldehyde Acetals. Advanced Synthesis & Catalysis. doi:10.1002/adsc.201800669. Supporting Information.
- ^ J. Org. Chem. 2009, 74, 12, 4490–4498. doi:10.1021/jo9006249
- ^ Pd-Catalyzed Decarboxylative Cross-Coupling of N-Aryl Anthranilic Acids to Access Carbazoles: Gram Scale Total Synthesis of Anti- Cancer Drug Ellipticine. Asian Journal of Organic Chemistry. 2023. doi:10.1002/ajoc.202300429.
- ^ Shin, Chang Hwan; Kim, Gong Gyeom; Heo, Jeong O; Chun, Min Seung; Kim, Dong Heon. Heterocyclic compounds as organic light-emitting device materials. 2015. KR2015027720.