1,3,5-三(4-羧基苯乙炔基)苯
外觀
1,3,5-三(4-羧基苯乙炔基)苯 | |
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識別 | |
CAS號 | 205383-17-1 |
SMILES |
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性質 | |
化學式 | C33H18O6 |
摩爾質量 | 510.49 g·mol−1 |
外觀 | 白色固體[1] |
熔點 | 352 °C[2] |
溶解性(水) | 1.4×10−3 g/L(25 °C)[3] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1,3,5-三(4-羧基苯乙炔基)苯是一種有機化合物,化學式為C33H18O6。它可由4-碘苯甲酸甲酯和1,3,5-三乙炔基苯在鈀催化下於三乙胺中反應、在四氫呋喃水溶液中由氫氧化鋰(或氫氧化鉀[1])水解後再酸化製得。[2]它可以用於構築金屬有機框架材料。[2][1][4]
參考文獻
[編輯]- ^ 1.0 1.1 1.2 Qingxia Yao. Series of Highly Stable Isoreticular Lanthanide Metal–Organic Frameworks with Expanding Pore Size and Tunable Luminescent Properties. Chem. Mater. 2015, 27, 15, 5332–5339. doi:10.1021/acs.chemmater.5b01711.
- ^ 2.0 2.1 2.2 Furukawa, Hiroyasu; et al. Ultrahigh Porosity in Metal-Organic Frameworks. Science (2010), 329(5990), 424-428. doi:10.1126/science.119216.
- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2024 ACD/Labs). Retrieved from SciFinder. [2024-04-03].
- ^ Andrei Andreichenko. Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids. Inorg. Chem. 2023, 62, 20, 7982–7992. doi:10.1021/acs.inorgchem.3c00881.