跳至內容

5-癸酮

維基百科,自由的百科全書
5-癸酮
英文名 5-decanone
識別
CAS號 820-29-1  checkY
PubChem 13175
SMILES
 
  • CCCCCC(=O)CCCC
InChI
 
  • InChI=1S/C10H20O/c1-3-5-7-9-10(11)8-6-4-2/h3-9H2,1-2H3
InChIKey JDPQWHLMBJZURR-UHFFFAOYSA-N
性質
化學式 C10H20
摩爾質量 140.27 g·mol−1
沸點 84—86 °C(357—359 K)(8 mmHg)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

5-癸酮(英語:5-decanone)是一種有機化合物,化學式C10H20O,可見於石榴[2]等物種。它可由5-癸醇德語5-Decanol在催化下氧化製得[3],或由己醯氯英語Hexanoyl chloride正丁基氯化鎂德語Butylmagnesiumchlorid(或正丁基鋰[4])反應得到。[5]

參考資料

[編輯]
  1. ^ G. Forrest Woods; Henry F. Lederle. The Chemistry of Pentadienal and its Derivatives. J. Am. Chem. Soc. 1951, 73, 5, 2245–2247. doi:10.1021/ja01149a093.
  2. ^ A.M.M. Costa; L.O. Silva. Chemical composition of commercial cold-pressed pomegranate (Punica granatum) seed oil from Turkey and Israel, and the use of bioactive compounds for samples’ origin preliminary discrimination. Journal of Food Composition and Analysis. 2018-09, 75. doi:10.1016/J.JFCA.2018.09.004. 
  3. ^ Park, Kwihwan; Jiang, Jing; Yamada, Tsuyoshi; Sajiki, Hironao. Ruthenium-on-carbon-catalyzed facile solvent-free oxidation of alcohols: efficient progress under solid-solid (liquid)-gas conditions. Source Chemical & Pharmaceutical Bulletin, 2021. 69 (12): 1200-1205. doi:10.1248/cpb.c21-00749.
  4. ^ Jae Kyo Park , Won Kyu Shin , Duk Keun An. An effective one-pot conversion of acid chlorides to aldehydes and ketones. Tetrahedron Letters, 2013. 54 (24): 3199-3203. doi:10.1016/j.tetlet.2013.04.041.
  5. ^ Maria Michela Dell'Anna; Piero Mastrorilli, Cosimo F Nobile, Giuseppe Marchese, Maria Rosaria Taurino. Coupling reactions between acyl chlorides and Grignard reagents in the presence of a supported Fe(III)-complex. Journal of Molecular Catalysis A: Chemical, 2000. 161 (1-2): 239-243. doi:10.1016/S1381-1169(00)00268-5.