二(2-甲基咪唑-1-基)甲烷
| 二(2-甲基咪唑-1-基)甲烷 | |
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| 识别 | |
| CAS号 | 111128-04-2 
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| SMILES |
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| 性质 | |
| 化学式 | C9H12N4 |
| 摩尔质量 | 176.22 g·mol−1 |
| 外观 | 无色块状晶体[1] |
| 密度 | 1.276 g·cm−3 |
| 熔点 | 174—176 °C（447—449 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
二(2-甲基咪唑-1-基)甲烷是一种有机化合物，化学式为C9H12N4。它可作为配体和金属盐反应，生成配合物。[2][3]
合成
[编辑]将2-甲基咪唑和氢氧化钠混合，加入二氯甲烷或二溴甲烷后加热反应得到产物，产物通过升华法提纯。[4]
二(咪唑-1-基)甲烷经正丁基锂锂化后与硫酸二甲酯反应，也可制得该化合物。[5]
参考文献
[编辑]- ^ 1.0 1.1 Chuan-Ming Jin, Chu-Ru Gong. Bis(2-methylimidazol-1-yl)methane. Acta Crystallographica Section E Structure Reports Online. 2005-05-15, 61 (5): o1494–o1495 [2020-11-18]. ISSN 1600-5368. doi:10.1107/S160053680501247X. （原始内容存档于2020-02-22）. （页面存档备份，存于互联网档案馆）
- ^ Tianqi Jin, Junqiang Zhou, Yangyang Pan, Yu Huang, Chuanming Jin. Self-assembled 1D infinite inorganic [2]catenane and 2D sheet framework with calix[8]phenylazoimidazole and [4+4]metallomacrocyclic motifs based on silver and ditopic bis(imidazolyl)methane ligands. Journal of Molecular Structure. 2018-05-15, 1160: 222–226 [2020-11-18]. ISSN 0022-2860. doi:10.1016/j.molstruc.2018.02.011.
- ^ Chuan-Ming Jin, Zhu Zhu, Ming-Xia Yao, Xiang-Gao Meng. In situreduction from CuX2 (X = Br, Cl) to Cu(I) halideclusters based on ligand bis(2-methylimidazo-1-yl)methane. CrystEngComm. 2010, 12 (2): 358–361 [2020-11-18]. ISSN 1466-8033. doi:10.1039/B915584H （英语）.
- ^ Kun-Peng Zhang, Tian-Qi Jin, Jun-Qiang Zhou, Ting-Ting Ma, Chuan-Ming Jin. Syntheses of Symmetric and Unsymmetric Bis-imidazole Derivatives Using Phase-Transfer Catalysis: Syntheses of Symmetric and Unsymmetric Bis-imidazole Derivatives. Journal of Heterocyclic Chemistry. 2017-11, 54 (6): 3065–3070 [2020-11-18]. doi:10.1002/jhet.2917 （英语）.
- ^ Xiang Zhao, Tao Wu, Xianhui Bu, Pingyun Feng. A mixed ligand route for the construction of tetrahedrally coordinated porous lithium frameworks. Dalton Transactions. 2011, 40 (32): 8072 [2020-11-18]. ISSN 1477-9226. doi:10.1039/c1dt10859j （英语）.