4-氯乙苯
| 4-氯乙苯 | |
|---|---|
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| 识别 | |
| CAS号 | 622-98-0 
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| SMILES |
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| 性质 | |
| 化学式 | C8H9Cl |
| 摩尔质量 | 140.61 g·mol−1 |
| 沸点 | 185 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
4-氯乙苯是一种有机氯化合物，化学式为C8H9Cl。它可由乙苯和次氯酸叔丁酯在沸石存在下于乙腈中反应制得，该反应会产生少量的2-氯乙苯。[2]
反应
[编辑]4-氯乙苯和过氧化叔丁醇在氯化铜、新铜试剂的催化下反应，可以得到4'-氯苯乙酮。[3]
参考文献
[编辑]- ^ Ignacio Aracil, Rafael Font, and Juan A. Conesa. Chlorinated and Nonchlorinated Compounds from the Pyrolysis and Combustion of Polychloroprene. Environ. Sci. Technol. 2010, 44, 11, 4169–4175. doi:10.1021/es100023a. S.I. pp S4.
- ^ Smith, Keith; Butters, Michael; Nay, Barry. Highly para-Selective Mono-Chlorination of Aromatic Compounds Under Mild Conditions by t-Butyl Hypochlorite in the Presence of Zeolites. Synthesis, 1985 (12), 1157–1158. doi:10.1055/s-1985-31462
- ^ Md. Munkir Hossain, Shin-Guang Shyu. Biphasic copper-catalyzed C–H bond activation of arylalkanes to ketones with tert-butyl hydroperoxide in water at room temperature. Tetrahedron. 2016. 72 (29). doi:10.1016/j.tet.2016.05.066.