四(4-硼酸基苯基)甲烷

四(4-硼酸基苯基)甲烷
识别
CAS号	153035-55-3
性质
化学式	C25H24B4O8
摩尔质量	495.70 g·mol⁻¹
密度	1.41±0.1 g·cm−3
溶解性（水）	0.041 g·L−1（25 °C，pH = 6.38）
pKa	7.79±0.16
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四(4-硼酸基苯基)甲烷是四苯甲烷中苯环对位的氢被-B(OH)₂取代而成的有机化合物，化学式为C₂₅H₂₄B₄O₈。它可以四(4-溴苯基)甲烷为原料，与硼酸三甲酯^[2]或联硼酸频那醇酯^[3]在一定条件下反应得到。该化合物具有有机硼酸的通性，如在钯化合物的催化下发生Suzuki反应来得到碳链增长的化合物，例如和二卤代芳烃之间的反应，生成共价有机框架材料（COF）^[4]；目前已知的进行量子效应实验的最多原子数的分子也是由此合成的。^[5]

其甲硅烷的类似物已被制得。^[6]

参考文献

^ ^1.0 ^1.1 ^1.2 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-10-9]
^ Lei Zhang, Jin‐Shi Sun, Fuxing Sun, Peng Chen, Jia Liu, Guangshan Zhu. Facile Synthesis of Ultrastable Porous Aromatic Frameworks by Suzuki–Miyaura Coupling Reaction for Adsorption Removal of Organic Dyes. Chemistry – A European Journal. 2019-03-12, 25 (15): 3903–3908 [2019-10-09]. ISSN 0947-6539. doi:10.1002/chem.201805713 （英语）. . Supporting Information. (PDF)
^ Luke A. Baldwin, Jonathan W. Crowe, David A. Pyles, Psaras L. McGrier. Metalation of a Mesoporous Three-Dimensional Covalent Organic Framework. Journal of the American Chemical Society. 2016-11-23, 138 (46): 15134–15137 [2019-10-09]. ISSN 0002-7863. doi:10.1021/jacs.6b10316. （原始内容存档于2021-07-31）（英语）. . Supporting Information （页面存档备份，存于互联网档案馆） (PDF)
^ Hyung Joon Jeon, Jung Hoon Choi, Yeob Lee, Kyung Min Choi, Jung Hyo Park, Jeung Ku Kang. Highly Selective CO2-Capturing Polymeric Organic Network Structures. Advanced Energy Materials. 2012-02, 2 (2): 225–228 [2019-10-09]. doi:10.1002/aenm.201100648 （英语）.
^ Yaakov Y. Fein, Philipp Geyer, Patrick Zwick, Filip Kiałka, Sebastian Pedalino, Marcel Mayor, Stefan Gerlich, Markus Arndt. Quantum superposition of molecules beyond 25 kDa. Nature Physics. 2019-09-23 [2019-10-09]. ISSN 1745-2473. doi:10.1038/s41567-019-0663-9. （原始内容存档于2020-05-24）（英语）.
^ Marcus Rose, Andreas Notzon, Maja Heitbaum, Georg Nickerl, Silvia Paasch, Eike Brunner, Frank Glorius, Stefan Kaskel. N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalysts. Chemical Communications. 2011, 47 (16): 4814 [2019-10-09]. ISSN 1359-7345. doi:10.1039/c1cc10268k （英语）.

[ACD-1] 1.0 ^1.1 ^1.2 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-10-9]

[2] Lei Zhang, Jin‐Shi Sun, Fuxing Sun, Peng Chen, Jia Liu, Guangshan Zhu. Facile Synthesis of Ultrastable Porous Aromatic Frameworks by Suzuki–Miyaura Coupling Reaction for Adsorption Removal of Organic Dyes. Chemistry – A European Journal. 2019-03-12, 25 (15): 3903–3908 [2019-10-09]. ISSN 0947-6539. doi:10.1002/chem.201805713 （英语）. . Supporting Information. (PDF)

[3] Luke A. Baldwin, Jonathan W. Crowe, David A. Pyles, Psaras L. McGrier. Metalation of a Mesoporous Three-Dimensional Covalent Organic Framework. Journal of the American Chemical Society. 2016-11-23, 138 (46): 15134–15137 [2019-10-09]. ISSN 0002-7863. doi:10.1021/jacs.6b10316. （原始内容存档于2021-07-31）（英语）. . Supporting Information （页面存档备份，存于互联网档案馆） (PDF)

[4] Hyung Joon Jeon, Jung Hoon Choi, Yeob Lee, Kyung Min Choi, Jung Hyo Park, Jeung Ku Kang. Highly Selective CO2-Capturing Polymeric Organic Network Structures. Advanced Energy Materials. 2012-02, 2 (2): 225–228 [2019-10-09]. doi:10.1002/aenm.201100648 （英语）.

[5] Yaakov Y. Fein, Philipp Geyer, Patrick Zwick, Filip Kiałka, Sebastian Pedalino, Marcel Mayor, Stefan Gerlich, Markus Arndt. Quantum superposition of molecules beyond 25 kDa. Nature Physics. 2019-09-23 [2019-10-09]. ISSN 1745-2473. doi:10.1038/s41567-019-0663-9. （原始内容存档于2020-05-24）（英语）.

[6] Marcus Rose, Andreas Notzon, Maja Heitbaum, Georg Nickerl, Silvia Paasch, Eike Brunner, Frank Glorius, Stefan Kaskel. N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalysts. Chemical Communications. 2011, 47 (16): 4814 [2019-10-09]. ISSN 1359-7345. doi:10.1039/c1cc10268k （英语）.

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