四(4-硼酸基苯基)甲烷

四(4-硼酸基苯基)甲烷
識別
CAS號	153035-55-3
性質
化學式	C25H24B4O8
摩爾質量	495.70 g·mol⁻¹
密度	1.41±0.1 g·cm−3
溶解性（水）	0.041 g·L−1（25 °C，pH = 6.38）
pKa	7.79±0.16
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

四(4-硼酸基苯基)甲烷是四苯甲烷中苯環對位的氫被-B(OH)₂取代而成的有機化合物，化學式為C₂₅H₂₄B₄O₈。它可以四(4-溴苯基)甲烷為原料，與硼酸三甲酯^[2]或聯硼酸頻那醇酯^[3]在一定條件下反應得到。該化合物具有有機硼酸的通性，如在鈀化合物的催化下發生Suzuki反應來得到碳鏈增長的化合物，例如和二鹵代芳烴之間的反應，生成共價有機框架材料（COF）^[4]；目前已知的進行量子效應實驗的最多原子數的分子也是由此合成的。^[5]

其甲矽烷的類似物已被製得。^[6]

參考文獻

^ ^1.0 ^1.1 ^1.2 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-10-9]
^ Lei Zhang, Jin‐Shi Sun, Fuxing Sun, Peng Chen, Jia Liu, Guangshan Zhu. Facile Synthesis of Ultrastable Porous Aromatic Frameworks by Suzuki–Miyaura Coupling Reaction for Adsorption Removal of Organic Dyes. Chemistry – A European Journal. 2019-03-12, 25 (15): 3903–3908 [2019-10-09]. ISSN 0947-6539. doi:10.1002/chem.201805713 （英語）. . Supporting Information. (PDF)
^ Luke A. Baldwin, Jonathan W. Crowe, David A. Pyles, Psaras L. McGrier. Metalation of a Mesoporous Three-Dimensional Covalent Organic Framework. Journal of the American Chemical Society. 2016-11-23, 138 (46): 15134–15137 [2019-10-09]. ISSN 0002-7863. doi:10.1021/jacs.6b10316. （原始內容存檔於2021-07-31）（英語）. . Supporting Information （頁面存檔備份，存於互聯網檔案館） (PDF)
^ Hyung Joon Jeon, Jung Hoon Choi, Yeob Lee, Kyung Min Choi, Jung Hyo Park, Jeung Ku Kang. Highly Selective CO2-Capturing Polymeric Organic Network Structures. Advanced Energy Materials. 2012-02, 2 (2): 225–228 [2019-10-09]. doi:10.1002/aenm.201100648 （英語）.
^ Yaakov Y. Fein, Philipp Geyer, Patrick Zwick, Filip Kiałka, Sebastian Pedalino, Marcel Mayor, Stefan Gerlich, Markus Arndt. Quantum superposition of molecules beyond 25 kDa. Nature Physics. 2019-09-23 [2019-10-09]. ISSN 1745-2473. doi:10.1038/s41567-019-0663-9. （原始內容存檔於2020-05-24）（英語）.
^ Marcus Rose, Andreas Notzon, Maja Heitbaum, Georg Nickerl, Silvia Paasch, Eike Brunner, Frank Glorius, Stefan Kaskel. N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalysts. Chemical Communications. 2011, 47 (16): 4814 [2019-10-09]. ISSN 1359-7345. doi:10.1039/c1cc10268k （英語）.

[ACD-1] 1.0 ^1.1 ^1.2 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-10-9]

[2] Lei Zhang, Jin‐Shi Sun, Fuxing Sun, Peng Chen, Jia Liu, Guangshan Zhu. Facile Synthesis of Ultrastable Porous Aromatic Frameworks by Suzuki–Miyaura Coupling Reaction for Adsorption Removal of Organic Dyes. Chemistry – A European Journal. 2019-03-12, 25 (15): 3903–3908 [2019-10-09]. ISSN 0947-6539. doi:10.1002/chem.201805713 （英語）. . Supporting Information. (PDF)

[3] Luke A. Baldwin, Jonathan W. Crowe, David A. Pyles, Psaras L. McGrier. Metalation of a Mesoporous Three-Dimensional Covalent Organic Framework. Journal of the American Chemical Society. 2016-11-23, 138 (46): 15134–15137 [2019-10-09]. ISSN 0002-7863. doi:10.1021/jacs.6b10316. （原始內容存檔於2021-07-31）（英語）. . Supporting Information （頁面存檔備份，存於互聯網檔案館） (PDF)

[4] Hyung Joon Jeon, Jung Hoon Choi, Yeob Lee, Kyung Min Choi, Jung Hyo Park, Jeung Ku Kang. Highly Selective CO2-Capturing Polymeric Organic Network Structures. Advanced Energy Materials. 2012-02, 2 (2): 225–228 [2019-10-09]. doi:10.1002/aenm.201100648 （英語）.

[5] Yaakov Y. Fein, Philipp Geyer, Patrick Zwick, Filip Kiałka, Sebastian Pedalino, Marcel Mayor, Stefan Gerlich, Markus Arndt. Quantum superposition of molecules beyond 25 kDa. Nature Physics. 2019-09-23 [2019-10-09]. ISSN 1745-2473. doi:10.1038/s41567-019-0663-9. （原始內容存檔於2020-05-24）（英語）.

[6] Marcus Rose, Andreas Notzon, Maja Heitbaum, Georg Nickerl, Silvia Paasch, Eike Brunner, Frank Glorius, Stefan Kaskel. N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalysts. Chemical Communications. 2011, 47 (16): 4814 [2019-10-09]. ISSN 1359-7345. doi:10.1039/c1cc10268k （英語）.

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